Potassium is a critical nutrient for plant growth and vital for agriculture. Potash deposits are the primary source of potassium. Although stratabound potash deposits provide the majority of the world’s potash, potassium-enriched brines contain the most widely defined and in-development potash resources in Western Australia. Here, potash evaporites are obtained via the evaporation of potassium-enriched brines in the mining process.
Targeted ore types
In contrast to most global potash production, which is from ‘hard rock’ stratabound sources, potash can be extracted from brine or brine-related processes such as evaporation of inland and seawater derived brines, or the extraction of alunitic clays from acidic salt lake environments. The focus of this system is on the formation of inland potassium enriched brines that are near the surface within salt lakes, playas or paleovalleys. These brines form the resource for extraction of potash via onsite evaporation in the mining process. Compared with other forms of potash mining, this method has the disadvantages of relying on climate for evaporation and requiring larger tracts of land for extraction and evaporation operations. However, this method has a significant advantage in the economic production of SOP due to the chemistry of the brines, specifically the presence of sulfate. Along an evaporation circuit, halite will precipitate first leaving behind a brine enriched in potassium and sulfate, from which potassium sulfate minerals such as kainite (KMgSO4Cl·3H2O) and schoenite (K2Mg(SO4)2·6H2O) can be precipitated (Salt Lake Potash Ltd, 2016).
Mineralization process
Within Western Australia, the evaporite brine-related potash mineral system is associated with inland salt lakes, playas and paleovalleys. In this system, the potassium is predominantly sourced from the dissolution of potassium bearing minerals from the surrounding lithologies, then transported along surface and groundwater pathways with the source of the water flux being rainfall or groundwater (English et al., 2012; Border and Sawyer, 2014). Potassium is then concentrated in salt lakes, playas or paleovalleys, either as soluble minerals or within brines of neutral to high pH.
Critical features
Derived layers are grouped based on their critical features:
SOURCE – scavenging of potassium from country rocks by meteoric waters
PATHWAY – transportation of potassium-bearing fluids from source to trap, predominantly by groundwater systems
TRAP – formation of potassium-enriched brine pools in salt lakes, playas and paleovalleys, mainly via evaporative discharge
Mineral system analysis
The Mineral System Tree is the graphical display of a mineral systems analysis showing the link between critical/constituent processes and their recommended targeting features and GIS layers.
References
Border, S and Sawyer, L 2014, Evaporites and brines – geological, hydrological and chemical aspects of resource estimation: Applied Earth Science, v. 123, no. 2, p. 95–106, 13p., doi:10.1179/1743275814Y.0000000053.
English, P, Lewis, S, Bell, J, Wischusen, J, Woodgate, M, Bastrakov, E, Macphail, M and Kilgour, P 2012, Water for Australia’s arid zone - identifying and assessing Australia’s palaeovalley groundwater resources: Summary report: National Water Commission, Canberra, Waterlines Report Series 68.
Salt Lake Potash Ltd 2016, Scoping study confirms Lake Wells’ potential as a major low cost SOP project: Australian Securities Exchange, 29 August 2016: Salt Lake Potash Ltd, viewed 12 May 2022, 35p., <www.investi.com.au/api/announcements/so4/1391cf81-1c1.pdf>.
Recommended reading
Bastrakov, EN, Jaireth, S and Mernagh, TP 2013, Salt lake mineral systems, in A review of Australian salt lakes and assessment of their potential for strategic resources edited by TP Mernagh: Geoscience Australia, Record 2013/39, p. 101–126.
Bell, JG, Kilgour, PL, English, PM, Woodgate, MF and Lewis, SJ 2012, WASANT paleovalley map — Distribution of paleovalley in arid and semi-arid WA–SA–NT (1:4 500 000 scale): Geoscience Australia, Geoscience Thematic Map (Geocat No. 73980).
Border, S and Sawyer, L 2014, Evaporites and brines – geological, hydrological and chemical aspects of resource estimation: Applied Earth Science, v. 123, no. 2, p. 95–106, 13p., doi:10.1179/1743275814Y.0000000053.
Bowler, JM 1986, Spatial variability and hydrological evolution of Australian lake basins: Analogue for Pleistocene hydrological change and evaporite formation: Palaeogeography, Palaeoclimatology, Palaeoecology, v. 54, p. 21–41.
Caritat, P de, Bastrakov, EN, Jaireth, S, English, PM, Clarke, JDA, Mernagh, TP, Wygralak, AS, Dulfer, HE and Trafford, J 2019, Groundwater geochemistry, hydrogeology and potash mineral potential of the Lake Woods region, Northern Territory, Australia: Australian Journal of Earth
Sciences, v. 66, no. 3, p. 411– 430.
Clarke, CJ, George, RJ, Bell, RW and Hobbs, RJ 1998, Major faults and the development of dryland salinity in the western wheatbelt of Western Australia: Hydrology and Earth System Sciences, v. 2, no. 1, p. 77–91.
Clarke, J 2014, Potash in Australian acid salt lakes: Geoscience Australia, promotional brochure.
Clarke, M 2022, Evaporite brine-related potash: a mineral systems analysis: Geological Survey of Western Australia, Record 2022/15, 11p.
English, P, Lewis, S, Bell, J, Wischusen, J, Woodgate, M, Bastrakov, E, Macphail, M and Kilgour, P 2012, Water for Australia’s arid zone - identifying and assessing Australia’s palaeovalley groundwater resources: Summary report: National Water Commission, Canberra, Waterlines Report Series 68.
English, PM, Magee, JW and Clarke, JDA 2013, Review of Australian continental salt lakes, in A review of Australian salt lakes and assessment of their potential for strategic resources edited by TP Mernagh: Geoscience Australia, Record 2013/39, p. 25–90.
Geological Survey of Western Australia 2020, Potash: Investment opportunities, Western Australia: Geological Survey of Western Australia.
Magee, J 2009, Palaeovalley groundwater resources in arid and semi-arid Australia - a literature review: Geoscience Australia, Record 2009/3, 224p.
Mernagh, TP (editor) 2013, A review of Australian salt lakes and assessment of their potential for strategic resources: Geoscience Australia, Record 2013/39, 243p.
Mernagh, TP, Bastrakov, EN, Jaireth, S, Caritat, P de, English, PM and Clarke, JDA 2016, A review of Australian salt lakes and associated mineral systems: Australian Journal of Earth Sciences, v. 63, no. 2, p. 131–157, 28p., doi:10.1080/08120099.2016.1149517.
Orris, GJ 2011, Deposit model for closed-basin potash-bearing brines: U.S. Geological Survey, Open-File Report 2011-1283, 11p.
Roach, IC, Costelloe, MT and Jaireth, S 2014, AEM and its application to potash exploration in Australian salt lakes: Preview, v. 2014, no. 172, p. 51–58, 9p., doi:10.1071/PVv2014n172other.
Senior, A, Britt, A, Summerfield, D, Hughes, A, Hitchman, A, Cross, A, Sexton, M, Pheeny, J, Teh, M, Hill, J and Cooper, M 2021, Australia’s Identified Mineral Resources 2021: Geoscience Australia, Canberra, 55p.
Zientek, ML, Hammarstrom, JM and Johnson, K (editors) 2010, Potash - a global overview of evaporite-related potash resources, including spatial databases of deposits, occurrences, and permissive tracts, Scientific Investigations Report 2010-5090-S.